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By John Lee, David M. Hercules, Milton J. Cormier (auth.), Milton J. Cormier, David M. Hercules, John Lee (eds.)

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Phys. 16. E. Wigner, Phys. Rev. 73, 1002 (1948). 17. T. F. alley, Phys. Rev. 137, A1l6 (1965). 18. M. G. Evans and M. Po1anyi, Trans. Faraday Soc. 35, 178, 192, 195 (1939). 19. J. L. Magee, J. Chern. Phys. , 652 (1939); 20. K. J. Laidler, The Chemical Kinetics of Excited States (Clarendon PresS:-Oxford, 1955), p. R5: 21. A. C. Roach and M. S. Child, Mol. Phys . 22. W. S. Struve, Mol. Phys. (to be published). 23. P. Pechukas, J. C. Light, and C. Rankin, J. Chern. Phys. 44, 794 (1966). 24. D. M. IIercu1es, Accts.

Bardsley and F. Mandl, Rept. Prog. Phys. 16. E. Wigner, Phys. Rev. 73, 1002 (1948). 17. T. F. alley, Phys. Rev. 137, A1l6 (1965). 18. M. G. Evans and M. Po1anyi, Trans. Faraday Soc. 35, 178, 192, 195 (1939). 19. J. L. Magee, J. Chern. Phys. , 652 (1939); 20. K. J. Laidler, The Chemical Kinetics of Excited States (Clarendon PresS:-Oxford, 1955), p. R5: 21. A. C. Roach and M. S. Child, Mol. Phys . 22. W. S. Struve, Mol. Phys. (to be published). 23. P. Pechukas, J. C. Light, and C. Rankin, J. Chern.

This paper deals with two families of alkali reactions. Interpretations or speculations related to the electron-transfer process are emphasized rather than experimental aspects. One family involves collisional excitation without chemical reaction,1-6 or ~ A + X* D. R. HERSCH BACH 31 where the asterisk denotes electronic excitation and X = H2, N2, 02, C02, S02, C2H~, C6H6, etc. Here the alkali valence electron executes a "double-jump", first switching to the target molecule and then returning to the alkali.

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